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Originally Posted by aussie
As recommended you should "condition" new Li-ion batteries by running at least 3-5 full charge/discharge cycles. This gives the battery chemistry a chance to permeate all the twisty little passages .
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Whatever you do, DON'T do this. Full charge discharge cycles can actually damage the battery. The number of cycles you get from a lithium battery increases greatly if you only cycle it shallowly.
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Originally Posted by BatteryUniversity.com
Unlike nickel and lead-based batteries, a new lithium-ion pack does not need cycling through charging and discharging. Priming will make little difference because the maximum capacity of lithium-ion is available right from the beginning. Neither does a full discharge improve the capacity of a faded pack. However, a full discharge/charge will reset the digital circuit of a 'smart' battery to improve the state-of-charge estimation
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There are other ways to reset the smart circut. You can typically get to it through the boot-up command line (at least on sager/clevo notebooks). I think there was a funny key combinatation that you hold (note: not DOS command prompt, I think it's a BIOS function).
Another bit of informations about lithium batteries that few people know is that lithium batteries have a 3-5 year shelf life, independant of use. So if you don't use the battery it will eventually degrade anyways. Heat greatly accelerates the process.
Lithium batteries are often rated by the numbers of charge discharge cycles they can handle, Generally 100% - 10% charge gives you 500 cycles to 50% capacity. However, only discharging the battery to 60-40% charge extends the cycle life towards 1000 cycles.
This is all just off the top of my head.
Oh, by the way, the Nickel-Cadmium "Memory Effect" is a complete fallacy.